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Cement mortar with enhanced flexural strength and durability-related properties using
Qing LIU, Renjun LIU, Qiao WANG, Rui LIANG, Zongjin LI, Guoxing SUN
《结构与土木工程前沿(英文)》 2021年 第15卷 第1期 页码 99-108 doi: 10.1007/s11709-021-0721-0
关键词: acrylamide in situ polymerization interaction porosity durability
Yulan GAO, Xiangchen FANG, Zhenmin CHENG
《化学科学与工程前沿(英文)》 2011年 第5卷 第3期 页码 287-296 doi: 10.1007/s11705-010-0529-2
关键词: ex-situ presulfurization in situ presulfurization hydrotreating catalyst sulfur utilization ratio
Gas phase ethylene polymerization over SiO
Liuzhong LI, Aiyou HAO, Ruihua CHENG, Boping LIU
《化学科学与工程前沿(英文)》 2011年 第5卷 第1期 页码 89-95 doi: 10.1007/s11705-010-0558-x
关键词: UCC S-2 catalyst Al-alkyl co-catalyst gas-phase ethylene polymerization high density polyethylene
Yakai FENG, Haiyang ZHAO, Li ZHANG, Jintang GUO,
《化学科学与工程前沿(英文)》 2010年 第4卷 第3期 页码 372-381 doi: 10.1007/s11705-010-0005-z
关键词: biomimetic amphiphilic amphiphilic phosphorylcholine endothelial functional biomaterial
Haibo ZHANG,Yanping YANG,He LIU,Jie SONG,Shibin SHANG,Zhanqian SONG
《农业科学与工程前沿(英文)》 2017年 第4卷 第1期 页码 97-105 doi: 10.15302/J-FASE-2016115
关键词: dehydroabietic acid bulk polymerization kinetics autocatalytic kinetic model
Polyolefin-nanocomposites with special properties by in-situ polymerization
Walter Kaminsky
《化学科学与工程前沿(英文)》 2018年 第12卷 第3期 页码 555-563 doi: 10.1007/s11705-018-1715-x
Exceptionally strong polyolefin nanocomposites are synthesized by in-situ polymerization using soluble metallocene/methylaluminoxane (MAO) as catalysts in a two-step process. First, the soluble metallocene/MAO or other single site catalysts are absorbed on the surface of the nanofillers. Then by addition of ethene or propene, a polyolefin film is formed, covering the nanoparticles, layered silicates, or fibers. The resulting polyethylene and polypropylene nanocomposites are characterized by better physical and chemical properties such as stiffness, gas barrier properties, degradation temperatures, and crystallization rates. They show better mechanical properties than materials produced by mechanical blending. The thickness of the polyolefin can be controlled by the pressure of ethene or propene and by the polymerization time. Carbon fibers and carbon nanotubes are covered with isotactic or syndiotactic polypropylene. Because of the hydrophobic character of the carbon surface, the polymer is drawn on the fiber. This leads to a reinforced combined polymer with special properties. The crystallization temperature is 10 °C higher and therefore the crystallization rate up to 20 times faster than that of pure syndiotactic polypropylene. The form stability increases by 100% if 3 wt-% of carbon nanotubes are incorporated.
关键词: polyolefin nanocomposites metallocenes methylaluminoxane
The effect of altering crosslinker chemistry during interfacial polymerization on the performance of
《化学科学与工程前沿(英文)》 2023年 第17卷 第12期 页码 2025-2036 doi: 10.1007/s11705-023-2356-2
关键词: acid chlorides covalent crosslinking desalination linear aliphatic amine micropollutant removal thin film composite membranes
《环境科学与工程前沿(英文)》 2023年 第17卷 第6期 doi: 10.1007/s11783-023-1675-3
● Medium poly Al salts dominated the PAC residual salts with a rational dosage.
关键词: Coagulation/flocculation Hydroxyl-aluminum Hydrolysis reaction Reactor performance Activated sludge property Surface properties
Jingtao WANG, Jin ZHANG, Junjie HAN,
《化学科学与工程前沿(英文)》 2010年 第4卷 第1期 页码 26-36 doi: 10.1007/s11705-009-0292-4
关键词: core-shell monodisperse nucleation Microfluidic different technical
Jianmei Zou, Jianzhi Huang, Huichun Zhang, Dongbei Yue
《环境科学与工程前沿(英文)》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1297-y
关键词: Two-dimensional correlation spectroscopy (2D-COS) Humic substances (HSs) Humification Manganese dioxide Polyphenol
武冠英
《中国工程科学》 1999年 第1卷 第3期 页码 79-85
文章从合成橡胶的化学基础出发,叙述了合成橡胶工业二十世纪以来的过去、现状,并展望未来。着重讨论了合成化学基础及相应聚合工艺过程的进步这两方面的问题。指出合成橡胶化学基础中活性聚合、可控聚合,包括茂金属催化剂仍为近期的重点;气相聚合工艺将会得到较大的发展;高效聚合釜的研究仍是核心问题;环保问题应更受到重视。
李晓,张卫英,袁惠根
《中国工程科学》 2003年 第5卷 第1期 页码 69-73
在阐述反相微乳液聚合液滴成核及粒子增长机理的基础上,提出了丙烯酰胺反相微乳液聚合过程的物理模式,并对反相微乳液聚合模型化处理时的关键问题作了扼要讨论。
曹湘洪,张爱民
《中国工程科学》 2001年 第3卷 第7期 页码 59-63
总结了燕山石化溶液聚合合成橡胶节能技术和节能型橡胶的开发情况。通过改进催化体系,提高反应速度,提高反应器的生产能力,并在聚合反应器中采用带刮刀的搅拌器,同时改进聚合、凝聚、溶剂回收的部分工艺及设备,燕山石化顺丁橡胶的能耗不断下降,达到世界先进水平。溶液聚合合成橡胶凝聚过程热泵技术的工业化,使生产每吨胶可节约1MPa的低压蒸汽0.72t。橡胶溶液直接脱挥,聚丁二烯橡胶气相聚合工艺技术开发,溶聚丁苯橡胶(SSBR)、中乙烯基聚丁二烯橡胶、苯乙烯-异戊二烯-丁二烯橡胶(SIBR)、苯乙烯-丁二烯热塑性弹性体(SBS)等新型节能型合成橡胶的技术开发也在进行中,其中SSBR、SBS技术已经工业化。
Hanlong LIU, Xuanming DING
《结构与土木工程前沿(英文)》 2009年 第3卷 第2期 页码 240-240 doi: 10.1007/s11709-009-0100-8
Kun OUYANG, Yu HUANG, Haoyi CHEN, Tao LI, Fahai CAO, Dingye FANG
《化学科学与工程前沿(英文)》 2011年 第5卷 第1期 页码 67-73 doi: 10.1007/s11705-010-0541-6
关键词: glycerol aqueous-phase reforming 1 3-propanediol in-situ reduction
标题 作者 时间 类型 操作
Cement mortar with enhanced flexural strength and durability-related properties using
Qing LIU, Renjun LIU, Qiao WANG, Rui LIANG, Zongjin LI, Guoxing SUN
期刊论文
Development and application of ex-situ presulfurization technology for hydrotreating catalysts in China
Yulan GAO, Xiangchen FANG, Zhenmin CHENG
期刊论文
Surface modification of biomaterials by photochemical immobilization and photograft polymerization to
Yakai FENG, Haiyang ZHAO, Li ZHANG, Jintang GUO,
期刊论文
Synthesis and bulk polymerization kinetics of monomer dehydroabietic acid-(2-acryloyloxy-ethoxy)-ethyl
Haibo ZHANG,Yanping YANG,He LIU,Jie SONG,Shibin SHANG,Zhanqian SONG
期刊论文
The effect of altering crosslinker chemistry during interfacial polymerization on the performance of
期刊论文
in industrial-wastewater pre-treatment: role of residual aluminum hydrolyzed species with different polymerization
期刊论文
Synthesis of crystals and particles by crystallization and polymerization in droplet-based microfluidic
Jingtao WANG, Jin ZHANG, Junjie HAN,
期刊论文
Evolution of humic substances in polymerization of polyphenol and amino acid based on non-destructive
Jianmei Zou, Jianzhi Huang, Huichun Zhang, Dongbei Yue
期刊论文
Propagation characteristics of transient waves in low-strain integrity testing on cast-in-situ concrete
Hanlong LIU, Xuanming DING
期刊论文